"The Sailor Senshi Are Here!"

After Usagi's attempt to transform into Sailor Moon fails, the girls quickly transform into the Sailor Senshi to confront the monster-of-the-day, Nekonneru. Nekonneru threatens to take a little girl's pure heart crystal and the Senshi stand together and state in unison, "We won't let you do that! The Sailor Senshi are here!"
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Sailor Moon S Episode #91
The birth of a rod of love! Usagi's new transformation
Ai no rod tanjou! Usagi no shinhenshin